I wrote an article on the DFF that was going to be in Mustangs International Magazine 5 yrs ago, but Michael O'Leary, after having me edit it and re-edit it for about 6 months, decided to not use it.
In retrospect, I've learned SOOO much about not just the DFF, but the whole Mustang since then. I helped James William Marshall every-so-little with his new book "P-51B North American's Bastard Stepchild That Saved the 8th Air Force." I've read all except for the heavy-duty engineering stuff (I'm a retired pharmacist and an ex-GA pilot but NOT an engineer like Bill!) going back to manuscript copies over a year ago.
Back to your point about the "rear fuel tank," the 85 gal fuselage tank began being installed in the P-51Bs and Cs at their respective factories rather early in the War, and in the P-51Ds in both factories from Day One. When that tank was full, it put the center of gravity too far to the rear of the "envelope" and made flying it very "squirrely" until they burned off about 60 gal of it on takeoff and climbout. I am "in the corner" with the guys who say that the 85 gal fuel tank, when full, NEEDED a DFF for the plane to stay stable.
I love everything about the Mustang family ... all 15,000 of them!