Of the Shkas there was even a 3000 RPM version (that really unreliable), the normal Shkas fired at 1800 RPM, and about 1650 when synchronized, so about 50% more than a Browning 303. But, for a comparison of weapons designed in the same years, the MG-81 fired 1600 RPM without being a revolver. As for the ammo load, a Mig-3 had 750 round per weapon, so 27 second of fire, Less than a Bf109f, but much more than a early Spit.
For jamming consideration, it's strange to replace two Mgs with one, especially if, if one of the two Shkas is jammed, the remainant could fire two rounds for every round fired by the UBS (800 RPM).
From wiki also, it seems Soviets were unimpressed by the reliability of the Browning 303: The .303 variant equipped the Hawker Hurricanes delivered to Soviet Air Forces, during the Great Patriotic War. Soviet airmen compared them to Soviet ShKAS in terms of reliability: "But they often failed due to dust," recalled pilot Nikolai G. Golodnikov. "We tackled the problem gluing percale on all the machine-gun holes, and when you opened fire, bullets went right through. The machine guns became reliable then. They were of low efficiency when fired from distances of 150-300m".