Somewhere, in some declassified Cold War document (from the early-1970s), I ran across discussions analyzing the Soviet practice of using materials/construction in their canopy/windscreen that exceeded the normal US practice relative to aerodynamic heating. IIRC the MiG-23 and MiG-25 were the airframes under discussion. The use of high strength heat resistant glass in their canopies was talked about, in comparison to the tougher but significantly less heat resistant plastics used in the service models of the US aircraft. The high speeds of the MiG-23 and MiG-25 were of significant concern to the US higher-ups at the time, and it was wondered if the trend would continue, with a focus on what the US should be looking at for future designs.
The F-106 originally used glass in its windscreen, while the F-4 used glass in the center section of the windscreen, but both switched to full plastic windscreens at some point.