There were a number of test flights with a PR.XI with speeds up to ~Mach 0.92, one of which saw the propeller break off (the wings were damaged from very high G-forces after that), another where the supercharger exploded and others where the dive was completely successful.
A PR.XIX in the far east after the war recorded the highest altitude attained by a Spitfire. Over 50,000ft. At one point the aircraft went into an uncontrolled dive, the calculated maximum speed was Mach 0.96. But this was based on regular instruments, nut on special test instruments used in the earlier tests. I believe the aircraft survived that unscathed.