Phenolic sheets were used as insulators in pre-'60s electronics, even inside vacuum tubes. Also, Bakelite panels/moldings and thin wafers of ceramics. Often times components and soldering posts would be mounted on those insulator sheets, and if someone got ham handed soldering to a post, those resin based materials gave off pungent, noxious stinks ... distinctive to the type.I have bought some phenolic sheet for use in fabricating various electrical components.
It was common for a while to have copper coated phenolic boards that could be masked and etched to make prototype quantity printed circuit boards at home or for small labs. These kits were available via Edmunds Scientific or Tandy/Radio Shack.