As soon as Winter hit, yes. So in the 1890s as soon as water cooling was done.
Wood Alcohol was an early additive for ICE engine Radiators, but would evaporate, and needed to by topped off continuously for cold weather protection. most of the Radiators were vented, unpressurized at this point and no automatic thermostats with block bypasses.
Sometimes Glycerine was added, to reduce the corrosion issues that came along the alcohol/water mix.
Ethylene Glycol was getting popular in the early 1930s, that didn't evaporate, but didn't cool as well as pure water and still had some corrosion issues.