It had a "separation charge" that was supposed to eject the entire "stores package" (weapon and aux fuel tanks) out the aft end of the bomb bay. It didn't have enough oomph to reliably clear the slipstream, which was more powerful than had been calculated. On more than one occasion this charge was triggered by the jolt of a catapult launch, ejecting the "package" onto the flight deck. A more powerful charge was deemed unsafe, and by that time submarine launched ballistic missiles were beginning to take over the Vigilante's mission.
Ah. Actually makes sense--surprising, in a way.
But the other factor was the prevalent idea at the time that, since we had nukes, snd THEY had nukes, they next unpleasantness was going to leave glow-in-the-dark craters where the cities had been, so there was no real need for manned bombers of any kind--hence BUFFs on Social Security.