Sorry for the confusion, but as I understand it the electric primed ammunition was used for guns that needed to be sychronized and percusion primed ammo was used for guns that didn't need to be synchronized, through the prop guns and pehaps defensive weapons. The luftwaffe was concerned that ground crews might load the wrong ammo into the ammo bins if an aircraft used both types and render the gun/s with the wrong ammo useless for that flight.
To keep things simple they just segerageted the ammo by type of aircraft. 109 squadrons with through the prop guns got the non-sychro ammo (percusion) while the 190 squadrons with the wing root guns got the syncro ammo (electric). at least that is the story from Mr. Williams.