Because at that given RPM you are not going to build up speed to exceed Vne or Vmax.
I don't think that's how it works, but my knowledge of engines and propellers isn't the greatest so I'll leave it to the more knowledgeable folks.
Interestingly, with regards to the pilot's notes, the Barracuda I, II (Merlin 30 32) are as you describe, but the Barracuda II III (Merlin 32) notes give no mention of RPM, but say the dive should be entered with not less than +6lb./sq.in. boost to avoid gaining excess speed.
This indicates to me that the reason for the 2,000 rpm is due to a propeller damage/overspeeding issue: the smaller pitch range on the 3-bladed prop compared to the 4-bladed, 32 degree prop.
All this aside - in reading A&AEE dive bombing tests with the Barracuda II (merlin 32) the aircraft could be dived to 300 IAS with brakes deployed, 2000 rpm and 0lb boost.
A telling bit in the 'conclusions' of the report:
The limiting diving speed was reached in a near-vertical dive (entry being effected by a firm push force on the control column) after diving through 4000-5000 feet, and hence, if a steep diving technique is to be employed operationally, the height at which the dive is entered must not be more than 5000 feet approximately above the required pull-out height. This may limit the operational role of the aircraft.
This doesn't seem like an aircraft that can set a certain RPM and stop accelerating straight down.