Canada began receiving Hurricanes September 1938, South Africa by November 1938, Yugoslavia by December 1938 ... so it was possible.
It was certainly possible, but for every Hurricane that went to Britain's allies, it was one less for the RAF. The Hurricane was a finite resource.
I don't actually know if a more advanced fighter in the Polish air force would have made much of a difference - Shortround's right in that whatever it was would have to be in large numbers by September 1st. The Bf 109 was the best fighter in continental Europe and the LW bombers the most modern, but we also have to consider that it wasn't just superior airpower that defeated the Poles. A combined effort from the German armed forces - Blitzkrieg - the speed of Germany's advance caught everyone by surprise - in France and Russia subsequently. Although fighting continued into October, it is recognised that by September 17, the invasion was successful - that's seventeen days to take Poland out!
The Polish air force dispersed its fighters to satellite fields before the invasion so when the LW attacked its airfields, vital types were not wiped out. The Germans were quite surprised by the determination of the Polish pilots, largely because they weren't expecting such determined counter attacks, but it wasn't any more courage or more modern aeroplanes that could have saved Poland.
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