There are some points worth raising about how the availability of 100 octane fuel affected the performance of RAF fighters: According to Alfred Price:
The higher octane fuel allowed an increase in supercharger boost from +6 lbs to +12 lbs, without risk of detonation that would damage the engine. A pilot could select the additional boost for five minutes by advancing the throttle 'through the gate' to the fully forward position. The emergency power setting increased the maximum speed by 25 mph at sea level and 34 mph at 10,000 feet. It also improved the fighter's climbing performance between sea level and full-throttle altitude. (Spitfire Mark I/II Aces 1939-41 page 19)
According to Alex Harvey-Bailey
The Merlin in Perspective - the combat years the Merlin III generated 1,310 hp at 9,000 feet using +12 lbs compared with its normal rating of 1,030 hp using +6 lbs at 16,250 feet. There do not seem to be any + 12 lb figures for the Merlin XII of the Spitfire II or the Merlin XX of the Hurricane II.
Points worth noting:
1: So far I have not seen an analysis of how often +12 lbs boost was used during the battle - ie: how often did pilots resort to going through the gate and in what circumstances?
2: Con: The critical altitudes at which the +12 lbs boost had the most effect were well below the Merlin III's usual full-throttle height of about 16,000 feet - much of the combat during the battle took place at higher altitudes.
Pro: Even so the provision of 100 octane gave pilots an option during attack or evasion - the combat reports show that Luftwaffe aircraft were caught and shot down at lower altitudes after RAF pilots went through the gate; of course it would be impossible to know how many Luftwaffe aircraft were shot down or damaged because RAF fighters were able to use the extra boost, without going through every single combat report from both sides. Similarly it would be interesting to know how many RAF pilots lived to fight another day because they were able to use the extra boost.
3: Con: Pilots were limited to +12 lbs for a maximum of five minutes: if the extra boost was used pilots had to note this in the engine log book because it was considered to be an extra load on the engine. The engine mechanics had to check the engine and replace the wire to the throttle gate.
Below please find documentation related to 100 octane use by the RAF leading up to and during the Battle of Britain:
Emergency +12 lbs./sq. in. Boost Operation: Pilot's Notes, Merlin II, III and IV, 4th Edition, April 1940, page 6.
Mike Williams # 48. Apparently Morgan and Shacklady say that the life of a Merlin engine dropped from c. 100 hours to 10-20 hours - no documentary evidence provided, however.
Pro: Five minutes may not seem a long time, but in air to air combat where encounters usually lasted less than 1 minute it was more than enough.
Overall I would suggest that at times the effect of 100 octane fuel on the Battle of Britain in particular has been overstated. In some publications it has been cited as being
critical to the outcome. However, because the performance increases conferred on RAF fighters was below the heights at which most combat took place it would have only been effective in a limited number of situations. Because it provided RAF pilots with options they would have otherwise lacked, the provision of 100 octane fuel was a valuable added tool, but not absolutely critical.