Part of the Hindenburg disaster was due to the fabric envelope. It was "painted" with some of the standard aircraft "dopes" of the day which were highly flammable in their own right once they got going.
From Wiki so correction is welcome;
"Aircraft dope is a
plasticised lacquer that is applied to
fabric-covered aircraft (both full-size and
flying models[1]). It tightens and stiffens fabric stretched over airframes, which renders them airtight and weatherproof.
[2]
Typical doping agents include
nitrocellulose,
cellulose acetate and cellulose acetate butyrate. Liquid dopes are highly flammable; nitrocellulose, for instance, is also known as the explosive propellant "guncotton".
The bit about gun cotton might need some correction or clarification. Gun cotton was too violent to use as a propellant although it was used as an explosive in early under water mines and torpedoes as it is much less sensitive to water/dampness. There are nitrocellulose propellants but the the ratios or percentage of the basic chemicals are different.
The HIndenburg fire was also fueled by the pigment used in the "dope". To get that nice shiny silver color powdered aluminum was put in the paint/dope.
Before somebody gets the bright idea of using camouflage paint on a Zeppelin they wanted a light reflective color so as to minimize the heating of the envelope from the sun during daylight. The higher temperatures would cause the gas to expand and give more lift (the gas bags usually had some slack in them) and gas would have to be vented to prevent the airship from rising. Problem then comes at night when the gas cools off, the bags shrink and lift is lost. How much spare hydrogen must be carried?
Some airships had systems that would recover the water from the exhaust of the engines (the Hindenburg did not) to use as ballast to partially compensate for the fuel being burned off so they wouldn't have to vent as much lifting gas (of either type) as the airship got lighter.
What was done in WW I on cross channel flights might not work so well on trans Atlantic flights (or "
patrols" of several days)
If it was avgas instead of Hydrogen then that would have been less likely.
Helium is inert and so has no risk of fire.
Any large aircraft in WW2 faced with a well armed fighter is going to be in for rough ride. It would be something to do a statistics analysis of the Zeppelin v a Gotha on which was the better bet in UK raids during ww1.
In my view the use of Hydrogen is a calculated risk which is no worse that avgas. Or the Germans were stupid.
If you replaced the hydrogen with avgas the thing would have never gotten out of the hanger
You are missing the point about the volume/target size. The Fuel tanks on many WW II aircraft are only a small percentage of the internal volume. Many aircraft took dozen of hits without any hitting the fuel tank/s, others were not so lucky. While the Hydrogen bags did not fill 100% of the envelope of a Zeppelin they did occupy a very large percentage of the internal volume.
The British did some testing at the start of WW II and found that the old WW I incendiary ammunition only set fire to Blenheim fuel tanks (fired at from the rear at about 200yds range) with about 1 round in 10 (tens hits were needed to set the tank/wing section on fire) the new incendiary ammo needed 5 rounds to start a fire on average.
One should note that the Germans pretty much stopped using Zeppelins to attack London in early 1917. there were 22 raids in 1916, there were 6 in 1917. a few of the 6 raids went on through the summer but the Gothas took over.
See this website for an account.
Defeating the Zeppelins | The National Archives
Yes it sometimes took 3 firing passes to set fire to a Zeppelin but that was using a single Lewis gun and no more than 300 rounds of ammo. There may have been other unsuccessful attacks.
A Blenheim fighter has 4-5 guns firing twice as fast and has 500 rounds for each gun.