All grades of petroleum/gasoline have a flash point, that is the temperature at which vapours are produced capable of making an ignitable mixture in air, well below zero celsius. Unless your cockpit temperature is below about -20 degrees celsius, whatever the octane rating of your fuel, the potential for going up in a fire ball when you strike that match exists.
Kerosene, Diesel and jet fuels have flash points in the region of +40 to +60 degrees Celsius, depending on their composition. That's why at normal ambient temperatures you can chuck a lighted match into the stuff with no fire or explosion. The ignitable vapour/air mixture is not present.
Smoking attenuates the amount of oxygen that diffuses from the lung tissue and oxygenates the blood. High altitude attenuates the amount of oxygen available for transport to the blood. A 2003 study suggested that these two hypoxic conditions react exponentially to affect human performance. The study concluded that "the combined hypoxic effects of smoking and high altitude result in a statistically significant detriment in pilot effective performance."
Don't smoke and fly at high altitude, or climb Everest. In fact just don't smoke!
Cheers
Steve