German Spitfires (that I know of):
Spitfire Mk.I Bogus British markings 'G-X' .Airworthy and used in propoganda photographs, with Badly positioned and proportioned roundels
Spitfire Mk.Ia ?-?? RAF camouflage with large Balkenkreuz (crosses) –Airworthy
Spitfire Mk.Ia RAF camo with overpainted codes and badly positioned and proportioned roundels applied, Airworthy and used in the famous 'Spitfire seen up close from an He111' propoganda photos.
Spitfie Mk.Ia '5+?' Bogus British markings, including badly positioned and proportioned roundels and fin-flashes. Airworthy and flown by Bf 109 pilots.
Spitfire Mk.V AZ-N ??277 'Duty Dick', ex 234 sqn. Emergency landed near Cherbourg. Retained RAF camo and serial, but codes lightly overpainted and large Balkenkreuz applied. Spit Mk.I metal prop. Airworthy
Spitfire Mk.V ?-?? EN830 'CJ+ZY' fitted with DB605A engine for comparitive flight testing
Spitfire MK.Vb SD-E AA837, ex 501 sqn. RAF camo, codes , serials, and A1 style roundels. Airworthy
Spitfire Mk.Vb RS-T . Robert Stanford-Tuck's personal aircraft, 29 kills. Brought down by ground fire during low level sweeps over the French beaches. RAF camo, A1 style roundels, wooden Jablo prop. Wrecked but repairable
Spitfire Mk.Vb AZ-B, ex 234 sqn. A1 roundels, Spit Mk.I metal prop. WBR
Spitfire Mk.Vb UZ-A AB364, ex 306 sqn. A1 style roundels.WBR
Spitfire PR.XI 'T9+ZB' large Balkenkreuz applied, Airworthy
Spitfire PR.XI 'T9+EK' large Balkenkreuz applied, Airworthy
Sources:
LuftArchiv.de - Das Archiv der Deutschen Luftwaffe –Beuteflugzeuge (captured aircraft);
Spifire in Action, Squadron signal No.39;
Die grossen Lutfschlacten des Zweiten Welt Kriegs –Kaiser Verlag;
Plus two other books – photocopied info, but didn't record book titles.
From one of them:
"By the beginning of the Battle of Britain the Germans had captured four Spitfires in flying or repairable condition"
... While according to 'Flugzeug Typen Der Welt' (Bechtermünz Verlag):
"The first Spitfires to be operated outside of the United Kingdom were Mk.V's, which were shipped on board the HMS Eagle to Malta on March 7th 1942"
Squadron Signal's 'Spitfire in Action' also mentions "tropicalized Spitfire Vb's sent to Malta...7 squadrons in the Mediterranean by June 1942".
Research on the net will no doubt give more info, I don't have time at the moment to check.
Evan