Shortround6
Major General
That is pretty much it but not exactly.I understand too much compression or heat causing detonation (premature ignition)
The entire intake charge is right of the verge of exploding if the temperature is too high. The temperature is the result of heating in the supercharger and heating in the cylinder if the charge is compressed.
In ordinary premature ignition something ( a hot spot or carbon deposit or....) ignites the mixture before the spark plug/s do but the mixture burns somewhat normally across the top of the piston or the flame front collides with advancing flame front from the spark plug/s causing a high pressure/high temperature hot spot.
If however the entire intake charge is hovering on the verge of ignition you may not get a traveling flame front across the cylinder but a near instantaneous explosion across the cylinder and sometimes before the piston has crossed top dead center. This is when you get bent/broken connecting rods and/or radial engine cylinders departing the rest of the engine for new locations. Sometimes it is a complete surprise and other times there are warning signs (noises)
With an supercharged engine it is a lot harder to wreck the engine, For one think it is very hard to the intake charge up to the auto ignite zone if the engine is running right or even close.
from the other direction, a supercharged engine running at 14.7lbs of boost as a it more than double the amount of fuel/air in the cylinder that a unsupercharged engine does (unsupercharged engines rarely have 100% volumetric efficiency unless highly tuned racing engines).
As an illustration Hurricane II with a Merlin XX engine at 20,000ft may be taking in air that is at 248 degrees C Absolute ( 25 degrees C below freezing) and yet the intake mixture in the manifold/s is at 394 degrees C Absolute ( 121 Degrees C above freezing or 21 degrees above boiling. Now put that hot mixture into the cylinders/s and compress at the nominal 6 to 1 compression ratio (neglecting valve timing).
This was the whole secret to high octane fuel. The higher the octane/PN the higher the autoignition temperature of the fuel and the less likely it was to detonate. Which allowed for more boost to be used to cram more fuel into the engine.