Thumpalumpacus
Major
POL fire?
"Petroleum/Oil/Lubricants" fire.
POLs are nasty fighting with pure water because they're all lighter than straight water. They will float on top of the water, and remain burning, and worse, the water can and will lift them above any local containment and aid the spread of the fire unless one is very careful.
AFFF (aqueous film-forming foam) lowers the specific gravity so that the mixture of foam and water will float atop any pooled liquid POLs, and because it's basically supercharged dish-soap, it will spread out, forming the film referred to in the name. In so doing, it separates the fuel from the oxygen and smothers the fire that way.
You still have to be very careful with AFFF, specifically taking care to never, repeat never, disturb your foam blanket once you've laid it down and gotten your smother on. In artillery terms, when shooting foam you're always shooting indirect fire, never direct fire. You rain the foam down onto the blaze using a fog setting on your nozzle or turret, no straight-streams allowed. You work to grow the blanket once you've blanketed the rescue side (port side of most a/c) or other egress paths that may be present.
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