In general, it's always better to mix paints and thinner in a separate container, stirring well, and then transfer to the cup. Mixing in the cup can result in an improper mix, with some of the thinner still in suspension, as a quantity of the mix will descend to the lowest level, in the gulley at the bottom of the cup.
Seeing as you've experienced drying in the nozzle/tip, and as these are acrylics, there's a strong chance that the needle has been coated with a thin film of paint, like a plastic membrane - one of the reasons I'm not that keen on acrylics.
This can cause spitting, feathering, splutter and all sorts of clogging problems, even though the 'coating' is microscopically thin. It's worth removing the needle and giving it a good clean - check it under a magnifying glass, and you should be able to see the coat of paint, and see when it's been cleaned off.